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By Abdelhamid Elaissari

ISBN-10: 0824743040

ISBN-13: 9780824743048

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98. 99. 100. 101. 102. 103. 104. 105. 106. 107. 108. 109. 110. 21 sions. Part III: Synthesis of concentrated latexes via classic emulsion polymerization. J. Appl. Polym. Sci. 2002, 84 (10), 1916–1934. F. High solids content emulsions. Part IV: Improved strategies for producing concentrated latexes. J. Appl. Polym. Sci. 2002, 84 (10), 1935–1948. ; Clarke, J. Ultrasensitive magnetic biosensor for homogeneous immunoassay. Proc. Natl. Acad. Sci. USA 2000, 97 (26), 14268–14272. ; Nie, S. Quantum-dot-tagged microbeads for multiplexed optical coding of biomolecules.

4. As a consequence, polymerization rate and molar mass can be adjusted independently with two parameters, namely, r and the initiator concentration. As shown above, the important parameter to control the kinetics was not directly the initiator concentration but the initial r = [SG1]0/[alkoxyamine]0 molar ratio. Indeed, the rate of propagation for the homopolymerization of a given monomer M can be expressed as: −d[M] = k p [Pؒ][M] = kp K([P-SG1]0 /[SG1])[M] dt (2) Controlled Free-Radical Polymerization 35 with kp, [Pؒ], K, and [P-SG1]0 the rate constant of propagation, the concentration of propagating macroradicals in the organic phase, the activation–deactivation equilibrium constant (Fig.

Nature 1997, 386, 410–414. Flamel Technologies. Fr. Pat. Appl. 95 03978. US Patent 5904936. ; Vauthier, C. Nanoparticles as drug delivery systems. ; Marcel Dekker: New York, 2002; 1874–1892. ; Matijevic, E. Mechanism of formation of monodispersed colloids by aggregation of nanosize precursors. J. Colloid. Interface Sci. 1999, 213, 36–45. ; Matijevic, E. Tailoring the particle size of monosizes colloidal gold. Colloids Surf A. Physicochem. Eng. Asp. 1999, 146, 139–152. P. Langmuir 1997, 13, 3927.

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Colloidal polymers: synthesis and characterization by Abdelhamid Elaissari

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