By Todd B. Marder, Zhenyang Lin
Content material: H. Braunschweig, C. Kollann, F. Seeler: Transition steel Borylene Complexes.- D.L. Kays, S. Aldridge: Transition steel Boryl Complexes.- Z. Lin: Transition steel Sigma-Borane Complexes.- M. Besora, A. Lledos: Coordination Modes and Hydride alternate Dynamics in Transition steel Tetrahydroborate Complexes
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Extra info for Borylenes, boryls, borane [sigma]-complexes, and borohydrides
The first term in the expansion has k = q = 0 and is spherically symmetric. This term gives the shift of spectral bands to the longer wavelength, as its influence on the upper levels is stronger than it is on the lower, more shielded levels. When only / electrons are involved, the terms in the expansion with k < 6 are nonzero. In addition, all terms with k odd vanish, hence it is the even terms in the expansion that reflect the splitting. The B~ can be regarded as coefficients of expansion to be determined empirically from AE, the magnitude of the splitting.
W. G. : Crystal Structures, Ed. 2, Wol. 3, pp. 325, 426. New York: Interscience Publishers 1965. 30. Hoard, f . , Stroupe, J. : paper 45, USAEC TID 5290 ]3ook I, 325--49 (1958). 48 Structural Systematics in Aetinide Fluoride Complexes 31. Asprey, L. , Keenan, T. , Penneman, R. , Sturgeon, G. D. : Inorg. Nucl. Chem. Letters 2, 19 (1966). 32. Penneman, R. , Sturgeon, G. , Asprey, L. , Kruse, F. H. : J. Am. Chem. Soc. 87, 5803 (1965). 33. Hepworth, M. , Jack, K. , Westland, G. f . : J. Inorg. Nucl.
147. 148. 149. 150. 151. 152. 153. 154. Zachariasen, W. H . : Acta Cryst. 2, 390 (1949). : Acta Cryst. B 25, 1919 (1969). Ryan, R. , Rosenzweig, A. : unpublished, Structure of CsU2F9 (1971). , Sears, D. ]~. : A c t a Cryst. t3 25, 2519 (1969). Penneman, R. , Ryan, R. , Kressin, I. K. : The Crystal structure of Ammonium I-Ieptafluorothorate, Acta Cryst. ]3 27, 2279 (1971). , Easey, J. , Holah, D. : J. Chem. Soc. (A) 1979 (1967). R. , t)enneman, R. , Rosenzweig, A. : Acta Cryst. 13 25, 1958 (1969).
Borylenes, boryls, borane [sigma]-complexes, and borohydrides by Todd B. Marder, Zhenyang Lin