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ISBN-10: 0470771585

ISBN-13: 9780470771587

ISBN-10: 0471996106

ISBN-13: 9780471996101

Content:
Chapter 1 contemporary advances within the theoretical therapy of acid derivatives (pages 1–58): I. G. Csizmadia, M. R. Peterson, C. Kozmutza and M. A. Robb
Chapter 2 Thermochemistry of acid derivatives (pages 59–66): Robert Shaw
Chapter three Chiroptical homes of acid derivatives (pages 67–120): Rolf Hakansson
Chapter four Mass spectra of acid derivatives (pages 121–174): S. W. Tam
Chapter five Complexes of acid anhydrides (pages 175–212): R. Foster
Chapter 6 Hydrogen bonding in carboxylic acids and derivatives (pages 213–266): Dusan Hadzi and Snegulka Detoni
Chapter 7 The synthesis of carboxylic acids and esters and their derivatives (pages 267–490): Michael A. Ogliaruso and James F. Wolfe
Chapter eight The chemistry of lactones and lactams (pages 491–531): G. V. Boyd
Chapter nine The chemistry of orthoamides of carboxylic acids and carbonic acid (pages 533–599): W. Kantlehner
Chapter 10 Detection and resolution of acid derivatives (pages 601–640): W. H. Prichard
Chapter eleven The photochemistry of natural acids, esters, anhydrides, lactones and imides (pages 641–753): Richard S. Givens and Nissim Levi

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Additional resources for Acid Derivatives: Volume 1 (1979)

Sample text

H- *C-H N/ H-C \ H N.... H - 0 \ 4 ' 0 C-H -z.... N 4 There is however a chance for non-cyclic dimerization. One of the geometrical arrangements studied by Dreyfus and Pullman' was as follows: H '* O \/ I N / \ H H \ N- / H H O0. e. 94 kcal/mole occurring a t an 0 . . 85 A, as 1. N DISTANCE Potential function for the linear hydrogen bonding of two formamide molecules. The optimum 0 . . N distance is 2-85 A. FIGURE 18. shown in Figure 18. This structure was relatively insensitive to geometrical variation.

20. H. Leblanc, Jr, V. W. Laurie and W. Gwinn, J. Chem. , 33,598 (1960). 21. The other structural parameters are determined consistently experimentally - see Table 1 of Reference 11.

3 "T and E refi2r to theoretical and experimental results respectively. bStandard geometry. =Optimized geometry. dExperimcnta1 geometry. Reference 47 16 8 8 8 22 49 50 26 I. G. Csizmadia, M. R. Peterson, C. Kozmutza and M. A. Robb TABLE 8. 50 41 42 51 8 8 8 49 52 O T and E stand for theoretical and experimental results respectively. %tandard geometry. Coptimizedgeometry. dExperimenta1geometry. (HOMO) is of n or n type. All results indicate that the IPS are close and Del Bene and coworkersa have shown that the results are strongly dependent on relatively small changes in the molecular geometry.

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