Chapter 1 contemporary advances within the theoretical therapy of acid derivatives (pages 1–58): I. G. Csizmadia, M. R. Peterson, C. Kozmutza and M. A. Robb
Chapter 2 Thermochemistry of acid derivatives (pages 59–66): Robert Shaw
Chapter three Chiroptical homes of acid derivatives (pages 67–120): Rolf Hakansson
Chapter four Mass spectra of acid derivatives (pages 121–174): S. W. Tam
Chapter five Complexes of acid anhydrides (pages 175–212): R. Foster
Chapter 6 Hydrogen bonding in carboxylic acids and derivatives (pages 213–266): Dusan Hadzi and Snegulka Detoni
Chapter 7 The synthesis of carboxylic acids and esters and their derivatives (pages 267–490): Michael A. Ogliaruso and James F. Wolfe
Chapter eight The chemistry of lactones and lactams (pages 491–531): G. V. Boyd
Chapter nine The chemistry of orthoamides of carboxylic acids and carbonic acid (pages 533–599): W. Kantlehner
Chapter 10 Detection and resolution of acid derivatives (pages 601–640): W. H. Prichard
Chapter eleven The photochemistry of natural acids, esters, anhydrides, lactones and imides (pages 641–753): Richard S. Givens and Nissim Levi
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Additional resources for Acid Derivatives: Volume 1 (1979)
H- *C-H N/ H-C \ H N.... H - 0 \ 4 ' 0 C-H -z.... N 4 There is however a chance for non-cyclic dimerization. One of the geometrical arrangements studied by Dreyfus and Pullman' was as follows: H '* O \/ I N / \ H H \ N- / H H O0. e. 94 kcal/mole occurring a t an 0 . . 85 A, as 1. N DISTANCE Potential function for the linear hydrogen bonding of two formamide molecules. The optimum 0 . . N distance is 2-85 A. FIGURE 18. shown in Figure 18. This structure was relatively insensitive to geometrical variation.
20. H. Leblanc, Jr, V. W. Laurie and W. Gwinn, J. Chem. , 33,598 (1960). 21. The other structural parameters are determined consistently experimentally - see Table 1 of Reference 11.
3 "T and E refi2r to theoretical and experimental results respectively. bStandard geometry. =Optimized geometry. dExperimcnta1 geometry. Reference 47 16 8 8 8 22 49 50 26 I. G. Csizmadia, M. R. Peterson, C. Kozmutza and M. A. Robb TABLE 8. 50 41 42 51 8 8 8 49 52 O T and E stand for theoretical and experimental results respectively. %tandard geometry. Coptimizedgeometry. dExperimenta1geometry. (HOMO) is of n or n type. All results indicate that the IPS are close and Del Bene and coworkersa have shown that the results are strongly dependent on relatively small changes in the molecular geometry.
Acid Derivatives: Volume 1 (1979)